Faculty Directory
Justin M. Notestein

Professor of Chemical and Biological Engineering

Contact

2145 Sheridan Road
Tech E250
Evanston, IL 60208-3109

847-491-5357Email Justin Notestein

Website

Notestein Research Group


Departments

Chemical and Biological Engineering


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Education

Post-doc Fellow Chemistry, University of Illinois at Urbana, Champaign, IL

Ph.D. Chemical Engineering, University of California, Berkeley, CA

B.S.E Chemical Engineering (magma cum laude), Princeton University, Princeton, NJ


Research Interests

Catalysis science, energy, materials and nanoscience

Catalytic materials are central to most industrial processes. We develop novel designs and syntheses of catalysts, adsorbents, and other functional materials especially for the purpose of more sustainable routes to important chemicals and fuels. We frequently collaborate with industry and national laboratories on such projects. We typically synthesize materials by modifying existing particle or MOF surfaces with organic functionalities (e.g. amines or carboxylates), inorganic complexes (e.g. Mn triazacyclononane, Ta calixarenes) or we build up additional, ultra-thin oxide layers. These groups are intended to control isolated or cooperative active sites consisting of acids, bases, redox groups, metals, and designed cavities in ways that can be difficult to engineer with traditional homogeneous or heterogeneous catalysts. The active sites on these new materials are also functional models for spectroscopy and simulation for the development of improved structure-function relationships. It is our guiding hypothesis that increasing control over - and diversity of - the active sites available for heterogeneous catalysts promises to yield new, more selective, and better understood chemical transformations. We have developed supported metal nanoparticle catalysts, oxide catalysts, immobilized molecular catalysts, and nanocavity catalysts. Chemical transformations currently being explored include selective oxidation, NO reduction, hydrotreating (hydrodenitrogenation and hydrodeoxygenation), photocatalysis, CO2 photoreduction, carbon capture and conversion, aldol condensation and related reactions, sugar and other biomass conversions, dehydration, decarboxylation, and selective adsorption of butanol and other molecules. An overarching long-term goal is to be able to design systems of active sites on a single surface capable of complex, efficient transformations of challenging molecules, in ways that mimic the connectivity of biological reaction pathways.


Selected Publications

  • Ahn, Sol; Nauert, Scott L.; Hicks, Kenton E.; Ardagh, M. Alexander; Schweitzer, Neil M.; Farha, Omar K.; Notestein, Justin M., Demonstrating the Critical Role of Solvation in Supported Ti and Nb Epoxidation Catalysts via Vapor-Phase Kinetics, ACS Catalysis
  • Barona, Melissa; Ahn, Sol; Morris, William; Hoover, William; Notestein, Justin M.; Farha, Omar K.; Snurr, Randall Q., Computational Predictions and Experimental Validation of Alkane Oxidative Dehydrogenation by Fe2M MOF Nodes, ACS Catalysis
  • Cheng, Emily; McCullough, Lauren; Noh, Hyunho; Farha, Omar; Hupp, Joseph; Notestein, Justin, Isobutane Dehydrogenation over Bulk and Supported Molybdenum Sulfide Catalysts, Industrial and Engineering Chemistry Research
  • Bo, Zhenyu; McCullough, Lauren R.; Dull, Samuel; Ardagh, M. Alexander; Wang, Jie; Notestein, Justin, Strong electrostatic adsorption of Pt onto SiO2 partially overcoated Al2O3 - Towards single atom catalysts, Journal of Chemical Physics
  • Bhagat, Mihir N.; Bennett, Charmaine K.; Chang, Gao Fong; Zhu, Youlong; Raghuraman, Arjun; Belowich, Matthew E.; Nguyen, Sonbinh T.; Broadbelt, Linda J.; Notestein, Justin M., Enhancing the Regioselectivity of B(C6F5)3-Catalyzed Epoxide Alcoholysis Reactions Using Hydrogen-Bond Acceptors, ACS Catalysis
  • Liu, Chao; Nauert, Scott L.; Alsina, Marco A.; Wang, Dingdi; Grant, Alexander; He, Kai; Weitz, Eric; Nolan, Michael; Gray, Kimberly A.; Notestein, Justin M., Role of surface reconstruction on Cu/TiO2 nanotubes for CO2 conversion, Applied Catalysis B: Environmental
  • Nauert, Scott L.; Rosen, Andrew S.; Kim, Hacksung; Snurr, Randall Q.; Stair, Peter C.; Notestein, Justin M., Evidence for Copper Dimers in Low-Loaded CuOx/SiO2 Catalysts for Cyclohexane Oxidative Dehydrogenation, ACS Catalysis
  • Ahn, Sol; Nauert, Scott L.; Buru, Cassandra T.; Rimoldi, Martino; Choi, Hyeju; Schweitzer, Neil M.; Hupp, Joseph T.; Farha, Omar K.; Notestein, Justin M., Pushing the Limits on Metal-Organic Frameworks as a Catalyst Support, Journal of the American Chemical Society
  • Griffin, James; Taw, Eric; Gosavi, Abha; Thornburg, Nicholas E.; Pramanda, Ihsan; Lee, Hyung Sool; Gray, Kimberly A.; Notestein, Justin M.; Wells, George, Hybrid Approach for Selective Sulfoxidation via Bioelectrochemically Derived Hydrogen Peroxide over a Niobium(V)-Silica Catalyst, ACS Sustainable Chemistry and Engineering
  • Bregante, Daniel T.; Thornburg, Nicholas E.; Notestein, Justin M.; Flaherty, David W., Consequences of Confinement for Alkene Epoxidation with Hydrogen Peroxide on Highly Dispersed Group 4 and 5 Metal Oxide Catalysts, ACS Catalysis
  • Yu, Ying; Zhu, Youlong; Bhagat, Mihir N.; Raghuraman, Arjun; Hirsekorn, Kurt F.; Notestein, Justin M.; Nguyen, Sonbinh T.; Broadbelt, Linda J., Mechanism of Regioselective Ring-Opening Reactions of 1,2-Epoxyoctane Catalyzed by Tris(pentafluorophenyl)borane, ACS Catalysis
  • McCullough, Lauren R.; Childers, David J.; Watson, Rachel A.; Kilos, Beata A.; Barton, David G.; Weitz, Eric; Kung, Harold H.; Notestein, Justin M., Acceptorless Dehydrogenative Coupling of Neat Alcohols Using Group VI Sulfide Catalysts, ACS Sustainable Chemistry and Engineering
  • Schwartzenberg, K. C.; Hamilton, J. W.J.; Lucid, A. K.; Weitz, E.; Notestein, J.; Nolan, M.; Byrne, J. A.; Gray, K. A., Multifunctional photo/thermal catalysts for the reduction of carbon dioxide, Catalysis Today
  • Ahn, Sol; Thornburg, Nicholas E.; Li, Zhanyong; Wang, Timothy C.; Gallington, Leighanne C.; Chapman, Karena W.; Notestein, Justin M; Hupp, Joseph T; Farha, Omar k, Stable metal-organic framework-supported niobium catalysts, Inorganic Chemistry
  • Grosso-Giordano, Nicolás A.; Eaton, Todd R.; Bo, Zhenyu; Yacob, Sara; Yang, Chieh Chao; Notestein, Justin M., Silica support modifications to enhance Pd-catalyzed deoxygenation of stearic acid, Applied Catalysis B: Environmental
  • Nauert, Scott L.; Schax, Fabian; Limberg, Christian; Notestein, Justin M., Cyclohexane oxidative dehydrogenation over copper oxide catalysts, Journal of Catalysis
  • Yang, Chieh Chao; Yacob, Sara; Kilos, Beata A.; Barton, David G.; Weitz, Eric; Notestein, Justin M., Increased productivity in ethylene carbonylation by zeolite-supported molybdenum carbonyls, Journal of Catalysis
  • Roberts, Charles A.; Savereide, Louisa; Childers, David J.; Peck, Torin C.; Notestein, Justin M, In situ FTIR spectroscopy of highly dispersed FeOx catalysts for NO reduction, Catalysis Today
  • Yacob, Sara; Kilos, Beata A.; Barton, David G.; Notestein, Justin M., Vapor phase ethanol carbonylation over Rh supported on zeolite 13X, Applied Catalysis A: General
  • Contreras, Christian A.; Ignacio-De Leon, Patricia Anne A.; Notestein, Justin M., Synthesis of a family of peracid-silica materials and their use as alkene epoxidation reagents, Microporous and Mesoporous Materials
  • Bachrach, Mark; Marks, Tobin Jay; Notestein, Justin M, Understanding the Hydrodenitrogenation of Heteroaromatics on a Molecular Level, ACS Catalysis
  • Ignacio-De Leon, Patricia Anne A.; Contreras, Christian A.; Thornburg, Nicholas E.; Thompson, Anthony B.; Notestein, Justin M., Catalyst structure and substituent effects on epoxidation of styrenics with immobilized Mn(tmtacn) complexes, Applied Catalysis A: General
  • Thornburg, Nicholas E.; Liu, Yangyang; Li, Peng; Hupp, Joseph T.; Farha, Omar K.; Notestein, Justin M., MOFs and their grafted analogues, Catalysis Science and Technology