Faculty Directory
Scott Barnett

Professor of Materials Science and Engineering

Contact

2220 Campus Drive
Cook Hall 2036
Evanston, IL 60208

Email Scott Barnett

Website

Scott Barnett Research Group


Departments

Materials Science and Engineering


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Education

Ph.D. Metallurgy, University of Illinois at Urbana, Champaign, IL

B.S. Physics, University of Illinois at Urbana, Champaign, IL


Research Interests

Barnett has worked extensively on ceramic thin films and coatings, including hard coatings and transparent conducting oxides. In the area of energy research, Barnett has been studying solid oxide fuel cells for > 20 years. His general areas of interest in fuel cells include novel processing methods including 3D printing and thin electrolyte deposition, electrode reaction mechanisms, intermediate-temperature solid oxide cells, direct utilization of hydrocarbon fuels, 3D imaging of electrode microstructure, and reversible cells for energy storage. The 3D imaging work includes pioneering studies connecting electrode processing methods to the resulting microstructure and in turn to the electrochemical characteristics.  He has also worked on studies of Li ion battery electrodes, including 3D tomographic imaging.  Recent research includes studies of reversible solid oxide cells for energy storage applications, and combined electrochemical and microstructural studies of electrode evolution over time, important for predicting the long-term durability of electrochemical devices. He has published more than 220 scientific journal articles, many highly cited, including articles in Science and Nature.  

 


Significant Recognition

  • Fulbright award, 2015
  • Otto Mønsted Guest Professorship, Danish Technical University, 2013
  • Cheng Tsang Man Endowed Professorship, Nanyang Technological University, Singapore, 2008
  • Fellow, American Vacuum Society (AVS), 1998
  • Department Teacher of the Year, 1993
  • Office of Naval Research Young Investigator Award, 1986

Selected Publications

    1  Zhu, T., Fowler, D. E., Poeppelmeier, K. R., Han, M. & Barnett, S. A. Hydrogen Oxidation Mechanisms on Perovskite Solid Oxide Fuel Cell Anodes. Journal of The Electrochemical Society 163, F952-F961, doi:10.1149/2.1321608jes (2016).

    2  Wang, H., Yakal-Kremski, K. J., Yeh, T., Rupp, G. M., Limbeck, A., Fleig, J. & Barnett, S. A. Mechanisms of Performance Degradation of (La,Sr)(Co,Fe)O3-δSolid Oxide Fuel Cell Cathodes. Journal of The Electrochemical Society 163, F581-F585, doi:10.1149/2.0031607jes (2016).

    3  Scipioni, R., Jørgensen, P. S., Ngo, D.-T., Simonsen, S. B., Liu, Z., Yakal-Kremski, K. J., Wang, H., Hjelm, J., Norby, P., Barnett, S. A. & Jensen, S. H. Electron microscopy investigations of changes in morphology and conductivity of LiFePO4/C electrodes. Journal of Power Sources 307, 259-269, doi:10.1016/j.jpowsour.2015.12.119 (2016).

    4  Liu, Z., Chen-Wiegart, Y. C., Wang, J., Barnett, S. A. & Faber, K. T. Three-Phase 3D Reconstruction of a LiCoO2 Cathode via FIB-SEM Tomography. Microsc Microanal 22, 140-148, doi:10.1017/S1431927615015640 (2016).

    5  Kennouche, D., Chen-Wiegart, Y.-c. K., Yakal-Kremski, K. J., Wang, J., Gibbs, J. W., Voorhees, P. W. & Barnett, S. A. Observing the microstructural evolution of Ni-Yttria-stabilized zirconia solid oxide fuel cell anodes. Acta Materialia 103, 204-210, doi:10.1016/j.actamat.2015.09.055 (2016).

    6  Kennouche, D., Chen-Wiegart, Y.-c. K., Riscoe, C., Wang, J. & Barnett, S. A. Combined electrochemical and X-ray tomography study of the high temperature evolution of Nickel – Yttria Stabilized Zirconia solid oxide fuel cell anodes. Journal of Power Sources 307, 604-612, doi:10.1016/j.jpowsour.2015.12.126 (2016).

    7  Gao, Z., Mogni, L. V., Miller, E. C., Railsback, J. G. & Barnett, S. A Perspective On Low-Temperature Solid Oxide Fuel Cells. Energy & Environmental Science, doi:10.1039/C5EE03858H (2016).

    8  Duffy, P. K., Barnett, S. A. & Mason, T. O. A Hemispherical Electrolyte Probe for Screening of Solid Oxide Fuel Cell Cathode Materials. Journal of The Electrochemical Society 163, F802-F807, doi:10.1149/2.0341608jes (2016).

    9  Call, A. V., Railsback, J. G., Wang, H. & Barnett, S. A. Degradation of nano-scale cathodes: a new paradigm for selecting low-temperature solid oxide cell materials. Physical chemistry chemical physics : PCCP 18, 13216-13222, doi:10.1039/c6cp02590k (2016).

    10  Yan, J., Gorai, P., Ortiz, B., Miller, S., Barnett, S. A., Mason, T., Stevanović, V. & Toberer, E. S. Material descriptors for predicting thermoelectric performance. Energy Environ. Sci. 8, 983-994, doi:10.1039/c4ee03157a (2015).

    11  Wendel, C. H., Gao, Z., Barnett, S. A. & Braun, R. J. Modeling and experimental performance of an intermediate temperature reversible solid oxide cell for high-efficiency, distributed-scale electrical energy storage. Journal of Power Sources 283, 329-342, doi:10.1016/j.jpowsour.2015.02.113 (2015).

    12  Wang, H., Gao, Z. & Barnett, S. A. Anode-Supported Solid Oxide Fuel Cells Fabricated by Single Step Reduced-Temperature Co-Firing. Journal of The Electrochemical Society 163, F196-F201, doi:10.1149/2.03716023jes (2015).

    13  Sumi, H., Kennouche, D., Yakal-Kremski, K., Suzuki, T., Barnett, S. A., Miller, D. J., Yamaguchi, T., Hamamoto, K. & Fujishiro, Y. Electrochemical and microstructural properties of Ni–(Y2O3)0.08(ZrO2)0.92–(Ce0.9Gd0.1)O1.95 anode-supported microtubular solid oxide fuel cells. Solid State Ionics, doi:10.1016/j.ssi.2015.07.005 (2015).

    14  Railsback, J. G., Gao, Z. & Barnett, S. A. Oxygen electrode characteristics of Pr2NiO4+δ-infiltrated porous (La0.9Sr0.1)(Ga0.8Mg0.2)O3–δ. Solid State Ionics 274, 134-139, doi:10.1016/j.ssi.2015.03.030 (2015).

    15  Miller, E. C., Sherman, Q., Gao, Z., Voorhees, P. W. & Barnett, S. A. in SOFC-XIV   (ed S.C. Singhal) (ECS Transactions Glasgow, 2015).

    16  Jensen, S. H., Graves, C., Mogensen, M., Wendel, C., Braun, R., Hughes, G., Gao, Z. & Barnett, S. A. Large-scale electricity storage utilizing reversible solid oxide cells combined with underground storage of CO2and CH4. Energy Environ. Sci. 8, 2471 - 2479, doi:10.1039/c5ee01485a (2015).

    17  Hughes, G. A., Railsback, J. G., Yakal-Kremski, K. J., Butts, D. M. & Barnett, S. A. Degradation of (LaSr)MnO-ZrYO composite electrodes during reversing current operation. Faraday Discuss, doi:10.1039/c5fd00020c (2015).

    18  Gao, Z., Zenou, V., Kennouche, D., Marks, L. D. & Barnett, S. Characteristics of Solid Oxide Cells with Zirconia/Ceria Bi-Layer Electrolytes Fabricated Utilizing Reduced-Temperature Firing. J. Mater. Chem. A, doi:10.1039/c5ta01964h (2015).

    19  Fowler, D. E., Messner, A. C., Miller, E. C., Slone, B. W., Barnett, S. A. & Poeppelmeier, K. R. Decreasing the Polarization Resistance of (La,Sr)CrO3−δSolid Oxide Fuel Cell Anodes by Combined Fe and Ru Substitution. Chem Mater, 150514130523002, doi:10.1021/acs.chemmater.5b00622 (2015).

    20  Yakal-Kremski, K., Mogni, L. V., Montenegro-Hernandez, A., Caneiro, A. & Barnett, S. A. Determination of Electrode Oxygen Transport Kinetics Using Electrochemical Impedance Spectroscopy Combined with Three-Dimensional Microstructure Measurement: Application to Nd2NiO4+delta. Journal of the Electrochemical Society 161, F1366-F1374, doi:Doi 10.1149/2.0521414jes (2014).

    21  Lu, Y., Kreller, C. R., Adler, S. B., Wilson, J. R., Barnett, S. A., Voorhees, P. W., Chen, H. Y. & Thornton, K. Performance Variability and Degradation in Porous La1-xSrxCoO3-  Electrodes. Journal of the Electrochemical Society 161, F561-F568, doi:10.1149/2.101404jes (2014).

    22  Kennouche, D., Hong, J., Noh, H.-S., Son, J.-W. & Barnett, S. A. Three-dimensional microstructure of high-performance pulsed-laser deposited Ni–YSZ SOFC anodes. Physical Chemistry Chemical Physics, doi:10.1039/c4cp02251c (2014).

    23  Jorgensen, P. S., Yakal-Kremski, K., Wilson, J., Bowen, J. R. & Barnett, S. On the accuracy of triple phase boundary lengths calculated from tomographic image data. Journal of Power Sources 261, 198-205, doi:Doi 10.1016/J.Jpowsour.2014.03.078 (2014).

    24  Gao, Z., Miller, E. C. & Barnett, S. A. A High Power Density Intermediate-Temperature Solid Oxide Fuel Cell with Thin (La0.9Sr0.1)(0.98)(Ga0.8Mg0.2)O3-delta Electrolyte and Nano-Scale Anode. Advanced Functional Materials 24, 5703-5709, doi:Doi 10.1002/Adfm.201400295 (2014).

    25  Gao, Z., Kennouche, D. & Barnett, S. A. Reduced-temperature firing of solid oxide fuel cells with zirconia/ceria bi-layer electrolytes. Journal of Power Sources 260, 259-263, doi:10.1016/j.jpowsour.2014.03.025 (2014).

    26  Gao, Z. & Barnett, S. A. Effects of Reduced Firing Temperature on Anode-Supported Solid Oxide Fuel Cells. Journal of the Electrochemical Society 161, F600-F604, doi:10.1149/2.033405jes (2014).

    27  Fowler, D. E., Haag, J., Boland, C., Bierschenk, D. M., Barnett, S. A. & Poeppelmeier, K. R. Stable, Low Polarization Resistance Solid Oxide Fuel Cell Anodes: La1-xSrxCr1-xFexO3-δ(x = 0.2 - 0.67). Chem Mater, 140428025107009, doi:10.1021/cm500423n (2014).

    28  Chen-Wiegart, Y.-c. K., DeMike, R., Erdonmez, C., Thornton, K., Barnett, S. A. & Wang, J. Tortuosity characterization of 3D microstructure at nano-scale for energy storage and conversion materials. Journal of Power Sources 249, 349-356, doi:10.1016/j.jpowsour.2013.10.026 (2014).